Synthesis and Reactivity of Thiolate-Bridged NiII MI Heterodinuclear Complexes (M = Rh, Ir) with an S-Bidentate NiP2 S2 Metalloligand
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Synthesis and dynamic behaviour of zwitterionic [M(η(6)-C6H5-BPh3)(coe)2] (M = Rh, Ir) cyclooctene complexes.
The synthesis and structural characterization of zwitterionic [(η(6)-C6H5-BPh3)M(coe)2] (M = Rh, Ir) cyclooctene complexes is described. Both complexes exhibit an unusual exo-endo conformation of both cyclooctene ligands in the solid state. However, an equilibrium between the endo-endo and exo-endo rotational isomers arising from the hindered rotation about the metal-cyclooctene bond is observe...
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2017
ISSN: 1434-1948
DOI: 10.1002/ejic.201700937